Hsiu-Hua Chang

Associate Professor,  Physical Chemistry

Phone:03-863-3595 (O)03-863-3596 (Lab.)

Fax: 03-863-3570  

E-mail: hhchang@mail.ndhu.edu.tw

Home Page   

Room: D422

National Dong Hwa University, Shou-Feng, Hualien, 974,  Taiwan                                                 


  • Education

1991: Ph. D., Department of Chemistry, Ohio State University, U. S. A.

 1985: B.C., Department of Chemistry, National Sun Yat-Sen University

 

  • Experience

Postdoctoral Research, Ohio state University

Postdoctoral Research, Vienna University

Postdoctoral Research, Academia Sinica

 

  • Research Interests

1. Theoretical Chemistry

2. Chemical Dynamics

3. Electronic Structure of Organometal and Molecular Clusters

4. Non-adiabatic Process

 

  • Selected Publications

     

    1. “A theoretical study on the reaction of ground state cyano radical with propylene in Titan’s atmosphere” by C. H. Huang, R. I. Kaiser, and A. H. H. Chang,* J. Phys. Chem. A (in press).
    2. “Synthesis of Interstellar 1,3,5-Heptatriynylidyne, C7H( X 2 ), via the Neutral-Neutral Reaction of Ground State Carbon Atom, C(3P), with Triacetylene, HC6H   (gX 1 )” by B. J. Sun, C. H. Huang, M. F. Tsai, H. L. Sun, L. G. Gao, Y. S. Wang, Y. Y. Yeh, Y. H. Shih, Z. F. Sia, P. H. Chen, R. I. Kaiser, and A. H. H. Chang,* J. Chem. Phys. 131, 104305 (2009).
    3. “Three-body Concerted Photodissociation for Acetyl Chloride Detected by Time-resolved Fourier-transform Infrared Spectroscopy”Yu-Ting Liu, Ming-Tsang Tsai, King-Chuen Lin,* Y. H. Shih and A. H. H. Chang (submitted).
    4. “Photodissociation of dibromoethanes at 248 nm: an ignored channel of Br2 elimination”Hsin-Lung Lee, Ping-Chen Lee, Po-Yu Tsai, King-Chuen Lin*, H. H. Kao, P. H. Chen, and A. H. H. Chang,* J. Chem. Phys. 130, 184308 (2009).
    5. “Br2 elimination in 248 nm photodissociation of 1,1-dibromoethylene probed bt cavity ring-down absorption spectroscopy”, P. C. Lee, P. Y. Tsai, M. K. Hsiao, K. C. Lin,* C. H. Huang, and A. H. H. Chang, Chem. Phys. Chem. 10, 672 (2009).

    6. “A crossed molecular beam study on the synthesis of the interstellar 2,4-pentadiynylidyne radical(HCCCCC)”, F. T. Zhang, Y. S. Kim, L. Zhou, R. I. Kaiser,* and A. H.H. Chang, J. Chem. Phys. 129, 134313 (2008).

    7. “Pathways to oxygen-bearing molecules in the interstellar medium and in planetary atmospheres: cyclopropenone (c-C3H2O) and propynal (HCCCHO)”, L. Zhou, R. I. Kaiser,* L. G. Gao, A. H. H. Chang, D. M. C. Liang, and Y. K. Yung, Astrophys. J. 686, 1493 (2008).

    8. “Formation of interstellar 2,4-pentadiynylidyne, HCCCCC(X2Π), via the neutral-neutral reaction of ground state carbon atom, C(3P), with diacetylene, HCCCCH     ( X 1 g )”, C. Y. Huang, B. J. Sun, H. H. Kuo, K. T. Chen, H. L. Sun, C. H. Huang, M. F. Tsai, C. H. Kao, Y. S. Wang, L. G. Gao, R. I. Kaiser, and A. H. H. Chang,* J. Chem. Phys. 128, 244303 (2008).

    9. “Photodissociation of 1,2-Dibromoethylene at 248 nm: Br2 molecular elimination probed by cavity ring-down absorption spectroscopy”, Y. P. Chang, P. C. Lee, K. C. Lin,* C. H. Huang, B. J. Sun, and A. H. H. Chang,* Chem. Phys. Chem.9, 1137 (2008).

    10. “A crossed beam and ab initio study on the reaction of Boron atoms, B(2Pj) with ethylene”, F. T. Zhang, X. B. Gu, R. I Kaiser,* N. Balucani, C. H. Huang, C. H. Kao, A. H. H. Chang, J. Phys. Chem. A112,3837 (2008).

    11. “Structural, photophysical, and catalytic properties of Au(I) complexes of 4-pyridines”, S.S. Tang, Chandra Sekhar Vasam, S.J. Hsu, Joseph C.Y. Lin, C.S. Lee, W. C. You, T. W. Ho, C. H. Huang, B. J. Sun, C. Y. Huang, W. S. Hwang , A. H. H. Chang,* I. J.B. Lin,* Inorg. Chem. 47, 2543 (2008)

    12. “A crossed molecular beams study on the reaction of Boron atoms, B(2Pj), with methylacetylene, CH3CCH(X1A1), and d3-methylacetylene, CD3CCH (X1A1)”, Fangtong Zhang, Chih Hao Kao, A. H. H. Chang, Xibin Gu, Y. Guo, R. I Kaiser,* Chem. Phys. Chem. 9, 95 (2008).

    13. “A crossed molecular beams study on the reaction of Boron atoms, B(2Pj), with allene, H2CCCH2(X1A1)”, F. T. Zhang, H. L. Sun, A. H. H. Chang, X. B. Gu, R. I Kaiser*, J. Phys. Chem. A 111, 13305 (2007).

    14. “Unraveling the formation of HCPH(X2A’) molecules in extraterrestrial environments - a crossed molecular beams study of the reaction of carbon atoms, C (3Pj), with phosphine, PH3 (X1A1)”, Y. Guo, X. Gu, F. Zhang, B. J. Sun, M. F. Tsai, A. H. H. Chang, R. I. Kaiser* J. Phys. Chem. A 111, 3241 (2007)

    15. "Br2 molecular elimination in 248 nm photolysis of CHBr2Cl by using cavity  ring-down absorption spectroscopy”, Pei-Ying Wei, Yuan-Ping Chang, Yu-Hsien Lee,Wei-Bin Lee, K. C. Lin,* K.T. Chen, and A. H. H. Chang J. Chem. Phys. 126, 034311 (2007).

    16. “Mechanistical studies of the irradiation of methanol in extraterrestrial ices”, C. J. Bennett, S. H. Chen, B. J. Sun, A. H. H. Chang, R. I. Kaiser* Astrophys. J. 660, 1588 (2007).

    17. “A crossed beams study of the carbon atoms, C(3Pj), with vinyl cyanides, C2H3CN (X1A’),- investigating the formation of cyano propargyl radicals”, Y. Guo, X. B. Gu, F. T. Zhang, M. S. Tang, B. J. Sun, A. H. H. Chang and R. I. Kaiser* Phys. Chem. Chem. Phys. 8, 5454 (2006).

    18. “248 nm photolysis of CH2Br2 by using cavity ring-down absorption spectroscopy: Br2 molecular elimination at room temperature”, P. Y. Wei, Y. P. Chang, W. B. Lee, Z. F. Hu, H. Y. Huang, K. C. Lin,* K. T. Chen, and A. H. H. Chang J. Chem. Phys. 125, 133319 (2006).

    19. "Reaction of cyanoacetylene HCCCN(X1Σ+) with ground state carbon atoms C(3P) in cold molecular clouds”, H. Y. Li, W. C. Cheng, Y. L. Liu, B. J. Sun, C. Y. Huang, K. T. Chen, M. S. Tang, R. I. Kaiser, and A. H. H. Chang* J. Chem. Phys. 124, 044307 (2006).

    20. "Gold (I) N-Heterocyclic Carbene and Carbazolate Complexes", H. M. J. Wang, C. S. Vasam, T. Y. R. Tsai, S. H. Chen, A. H. H. Chang,* and I. J. B. Lin* Organometallics 24, 486 (2005).